Long-term analysis of soil water regime and nitrate dynamics at agricultural experimental site : field-scale monitoring and numerical modeling using HYDRUS-1D
- Krevh, Vedran, Filipović, Lana, Petošić, Dragutin, Mustać, Ivica, Bogunović, Igor, Butorac, Jaminka, Kisić, Ivica, Defterdarović, Jasmina, Nakić, Zoran, Kovač, Zoran, Pereira, Paulo, He, Hailong, Chen, Rui, Toor, Gurpal, Versini, Antoine, Baumgartl, Thomas, Filipović, Vilim
- Authors: Krevh, Vedran , Filipović, Lana , Petošić, Dragutin , Mustać, Ivica , Bogunović, Igor , Butorac, Jaminka , Kisić, Ivica , Defterdarović, Jasmina , Nakić, Zoran , Kovač, Zoran , Pereira, Paulo , He, Hailong , Chen, Rui , Toor, Gurpal , Versini, Antoine , Baumgartl, Thomas , Filipović, Vilim
- Date: 2023
- Type: Text , Journal article
- Relation: Agricultural Water Management Vol. 275, no. (2023), p.
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- Description: Intensive agricultural practices increase agrochemical pollution, particularly nitrogen (N) based fertilizers, which present an environmental risk. This study aims to evaluate long-term (2009–2020) data on soil water regime and nitrate dynamics at an agricultural experimental site on fine-textured soils and to better understand the implications of N management in relation to groundwater pollution. The field site is located in the Biđ field (eastern Croatia), in the proximity of the Sava river. Zero-tension lysimeters were installed at six selected locations. Lysimeters were used to monitor the water regime, i.e., outflows in which nitrate concentration was measured, while additional soil-water samples were collected via 4 and 15-meter-deep monitoring wells. Soil hydraulic parameters were estimated by combining the laboratory measurements, and estimation in RETC software. Water regime and nitrate leaching in lysimeters were simulated using HYDRUS-1D for each year to allow crop rotation and to evaluate their effects individually. The HYDRUS-1D model successfully reproduced lysimeter outflows and nitrate dynamics, which was confirmed with high R2 values (water: 93% above 0.7, and nitrate: 73% above 0.7) indicating the good performance of the model simulating nitrification chain reactions. Principal component analysis (PCA) was performed to identify the relationships among all soil properties and environmental characteristics. The results showed the complex interaction of soil hydraulic properties, precipitation patterns, plant uptake, and N application. All locations have a decreasing trend of nitrate leaching over the investigation period. Most of the lysimeter outflows and elevated nitrate concentrations were connected to the wet period of the year when the soil was saturated, and evapotranspiration was low. The results of this study show that it is important to optimize N fertilizer applications for each particular environmental condition to reduce nitrate loss. The study indicates the importance of long-term field studies, key for agro-hydrological modeling and the improvement of agricultural practices. © 2022 The Authors
- Authors: Krevh, Vedran , Filipović, Lana , Petošić, Dragutin , Mustać, Ivica , Bogunović, Igor , Butorac, Jaminka , Kisić, Ivica , Defterdarović, Jasmina , Nakić, Zoran , Kovač, Zoran , Pereira, Paulo , He, Hailong , Chen, Rui , Toor, Gurpal , Versini, Antoine , Baumgartl, Thomas , Filipović, Vilim
- Date: 2023
- Type: Text , Journal article
- Relation: Agricultural Water Management Vol. 275, no. (2023), p.
- Full Text:
- Reviewed:
- Description: Intensive agricultural practices increase agrochemical pollution, particularly nitrogen (N) based fertilizers, which present an environmental risk. This study aims to evaluate long-term (2009–2020) data on soil water regime and nitrate dynamics at an agricultural experimental site on fine-textured soils and to better understand the implications of N management in relation to groundwater pollution. The field site is located in the Biđ field (eastern Croatia), in the proximity of the Sava river. Zero-tension lysimeters were installed at six selected locations. Lysimeters were used to monitor the water regime, i.e., outflows in which nitrate concentration was measured, while additional soil-water samples were collected via 4 and 15-meter-deep monitoring wells. Soil hydraulic parameters were estimated by combining the laboratory measurements, and estimation in RETC software. Water regime and nitrate leaching in lysimeters were simulated using HYDRUS-1D for each year to allow crop rotation and to evaluate their effects individually. The HYDRUS-1D model successfully reproduced lysimeter outflows and nitrate dynamics, which was confirmed with high R2 values (water: 93% above 0.7, and nitrate: 73% above 0.7) indicating the good performance of the model simulating nitrification chain reactions. Principal component analysis (PCA) was performed to identify the relationships among all soil properties and environmental characteristics. The results showed the complex interaction of soil hydraulic properties, precipitation patterns, plant uptake, and N application. All locations have a decreasing trend of nitrate leaching over the investigation period. Most of the lysimeter outflows and elevated nitrate concentrations were connected to the wet period of the year when the soil was saturated, and evapotranspiration was low. The results of this study show that it is important to optimize N fertilizer applications for each particular environmental condition to reduce nitrate loss. The study indicates the importance of long-term field studies, key for agro-hydrological modeling and the improvement of agricultural practices. © 2022 The Authors
Leached copper correlation with dissolved organic carbon in sloped vineyard soil
- Filipovi, Lana, Defterdarović, Jasmina, Chen, Rui, Krevh, Vedran, Gerke, Horst, Baumgartl, Thomas, Kovač, Zoran, Ondrašek, Gabrijel, Ružičić, Stanko, He, Hailong, Dusek, Jaromir, Filipović, Vilim
- Authors: Filipovi, Lana , Defterdarović, Jasmina , Chen, Rui , Krevh, Vedran , Gerke, Horst , Baumgartl, Thomas , Kovač, Zoran , Ondrašek, Gabrijel , Ružičić, Stanko , He, Hailong , Dusek, Jaromir , Filipović, Vilim
- Date: 2023
- Type: Text , Journal article
- Relation: Water (Switzerland) Vol. 15, no. 4 (2023), p.
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- Description: The solubility and mobility of copper (Cu) in soil is strongly influenced by the presence of dissolved organic carbon (DOC); however, the interactions between Cu and DOC are complex and not yet fully understood. In this study, Cu and DOC concentrations were measured monthly for two years in leachates from self-constructed lysimeters installed at inter- and intra-row vineyard hilltop, backslope, and footslope areas at the SUPREHILL Critical Zone Observatory, Croatia. The aim was to quantify Cu and DOC leaching from the hilltop towards the backslope and the footslope. The assumed strong relationship between Cu and DOC in the leachates was statistically analyzed and explained using chemical equilibrium software. Leachates were analyzed for pH, EC, DOC, Cu, and major ion concentrations. The highest Cu concentrations found in leachates from the intra-row footslope suggested Cu downhill transport. Although not strong, a significant positive correlation between Cu and DOC in footslope leachates confirmed the relevance of Cu complexation by DOC. Speciation confirmed that more than 99.9% of total Cu in leachates was found as a Cu-DOC complex. Data implied the role of soil water flow pathways in explaining Cu downhill transport. Critical timing for applying Cu fungicides at sloped vineyards was highlighted. © 2023 by the authors.
- Authors: Filipovi, Lana , Defterdarović, Jasmina , Chen, Rui , Krevh, Vedran , Gerke, Horst , Baumgartl, Thomas , Kovač, Zoran , Ondrašek, Gabrijel , Ružičić, Stanko , He, Hailong , Dusek, Jaromir , Filipović, Vilim
- Date: 2023
- Type: Text , Journal article
- Relation: Water (Switzerland) Vol. 15, no. 4 (2023), p.
- Full Text:
- Reviewed:
- Description: The solubility and mobility of copper (Cu) in soil is strongly influenced by the presence of dissolved organic carbon (DOC); however, the interactions between Cu and DOC are complex and not yet fully understood. In this study, Cu and DOC concentrations were measured monthly for two years in leachates from self-constructed lysimeters installed at inter- and intra-row vineyard hilltop, backslope, and footslope areas at the SUPREHILL Critical Zone Observatory, Croatia. The aim was to quantify Cu and DOC leaching from the hilltop towards the backslope and the footslope. The assumed strong relationship between Cu and DOC in the leachates was statistically analyzed and explained using chemical equilibrium software. Leachates were analyzed for pH, EC, DOC, Cu, and major ion concentrations. The highest Cu concentrations found in leachates from the intra-row footslope suggested Cu downhill transport. Although not strong, a significant positive correlation between Cu and DOC in footslope leachates confirmed the relevance of Cu complexation by DOC. Speciation confirmed that more than 99.9% of total Cu in leachates was found as a Cu-DOC complex. Data implied the role of soil water flow pathways in explaining Cu downhill transport. Critical timing for applying Cu fungicides at sloped vineyards was highlighted. © 2023 by the authors.
Quantification of intra- vs. inter-row leaching of major plant nutrients in sloping vineyard soils
- Filipović, Lana, Krevh, Vedran, Chen, Rui, Defterdarović, Jasmina, Kovač, Zoran, Mustać, Ivan, Bogunović, Igor, He, Hailong, Baumgartl, Thomas, Gerke, Horst, Toor, Gurpal, Filipović, Vilim
- Authors: Filipović, Lana , Krevh, Vedran , Chen, Rui , Defterdarović, Jasmina , Kovač, Zoran , Mustać, Ivan , Bogunović, Igor , He, Hailong , Baumgartl, Thomas , Gerke, Horst , Toor, Gurpal , Filipović, Vilim
- Date: 2023
- Type: Text , Journal article
- Relation: Water (Switzerland) Vol. 15, no. 4 (2023), p.
- Full Text:
- Reviewed:
- Description: Nutrient leaching from agricultural soils presents an economic loss for farmers and can degrade the quality of the surrounding environment. Thus, leachates from 18 in situ wick lysimeters, installed at 40 cm soil depth at the vineyard hilltop, backslope, and footslope intra- and inter-row area (SUPREHILL Critical Zone Observatory, Croatia) were collected monthly over two years and analyzed for major plant nutrient ions. Our objectives were to quantify nutrient losses via leaching from the hilltop towards the backslope and to the footslope, and to compare leaching from vine plant rows (intra-row) with grassed areas between vine rows (inter-row). We found that the concentrations of nitrate, orthophosphate, and potassium were significantly higher in leachates collected at the footslope as compared to the hilltop and backslope only at intra- and not at inter-row positions, while ammonium was independent of the slope and row positions. The vineyard intra-row is identified as the probable spatial origin of nutrient leaching along the slope, thus confirming spatially different contributions of overall hillslope to major plant nutrients leaching. The experimental field scheme used in this study, which separately analyses vineyard intra- and inter-row, was confirmed to be an adequate approach for optimizing vineyard management practices. © 2023 by the authors.
- Authors: Filipović, Lana , Krevh, Vedran , Chen, Rui , Defterdarović, Jasmina , Kovač, Zoran , Mustać, Ivan , Bogunović, Igor , He, Hailong , Baumgartl, Thomas , Gerke, Horst , Toor, Gurpal , Filipović, Vilim
- Date: 2023
- Type: Text , Journal article
- Relation: Water (Switzerland) Vol. 15, no. 4 (2023), p.
- Full Text:
- Reviewed:
- Description: Nutrient leaching from agricultural soils presents an economic loss for farmers and can degrade the quality of the surrounding environment. Thus, leachates from 18 in situ wick lysimeters, installed at 40 cm soil depth at the vineyard hilltop, backslope, and footslope intra- and inter-row area (SUPREHILL Critical Zone Observatory, Croatia) were collected monthly over two years and analyzed for major plant nutrient ions. Our objectives were to quantify nutrient losses via leaching from the hilltop towards the backslope and to the footslope, and to compare leaching from vine plant rows (intra-row) with grassed areas between vine rows (inter-row). We found that the concentrations of nitrate, orthophosphate, and potassium were significantly higher in leachates collected at the footslope as compared to the hilltop and backslope only at intra- and not at inter-row positions, while ammonium was independent of the slope and row positions. The vineyard intra-row is identified as the probable spatial origin of nutrient leaching along the slope, thus confirming spatially different contributions of overall hillslope to major plant nutrients leaching. The experimental field scheme used in this study, which separately analyses vineyard intra- and inter-row, was confirmed to be an adequate approach for optimizing vineyard management practices. © 2023 by the authors.
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