Distribution of metals and arsenic in soils of Central Victoria (Creswick-Ballarat), Australia
- Authors: Sultan, Khawar
- Date: 2007
- Type: Text , Journal article
- Relation: Archives of Environmental Contamination and Toxicology Vol. 52, no. 3 (2007), p. 339-346
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- Description: A soil-sampling campaign was conducted to identify and map heavy-metal contamination in the Ballarat-Creswick area of Central Victoria, Australia, with respect to mining activities and natural background levels in soils. The distribution and concentrations of both lithology- (Fe, Al, and Mn) and pollution-sensitive elements (Zn, As, Pb, Cu, Cr, Ni, and Co) were documented in surface soils (approximately 0 to 10 cm, fraction <2 mm, n = 85). The total heavy-metal and metalloid contents in soils decreased in the order Fe >> Al >> Zn > Mn >> As > Pb > Cu ≈ Ni ≈ Cr > Co. Mean levels of Zn (273 mg/kg) and As (39 mg/kg) in soils were well above normal global ranges and could be of local importance as a source of contamination. Extreme soil levels of Ni, Cr, Pb, and Fe were found in old mining waste material and pointed to the anthropogenic influence on the environment. Most of the measured elements showed marked spatial variations except Co. As contents were significantly higher than the tolerable level (ANZECC (1992) guidelines), with values up to 395.8 mg/kg around the mine tailings site. Mn soil contents were strongly associated with Co and Ni contents in most soils. High Fe contents (average approximately 41,465 mg/kg) in soils developed on basalt bedrock were correlated with Zn contents (average 400 mg/kg), and it is highly likely that Fe-oxides serve as sinks for Zn under near-neutral soil pH (6.3) conditions. Between the two major bedrock lithologic units, Ordovician sediments and Tertiary basalt, a clear enrichment of metals was found in the latter that was reflected in high background levels of elements. Among the various size fractions, silt (average approximately 45.1%) dominated most of the soils. In general and with a few exceptions, the concentrations of measured elements did not show significant correlations to other measured soil parameters, e.g., clay, silt and sand size fractions, organic matter, soil pH, and cation exchange capacity. © 2007 Springer Science+Business Media, Inc.
- Description: C1
- Description: 2003004769
Seasonal changes in arsenic concentrations and hydrogeochemistry of Canadian Creek, Ballarat (Victoria, Australia)
- Authors: Sultan, Khawar , Dowling, Kim
- Date: 2006
- Type: Text , Journal article
- Relation: Water, Air, and Soil Pollution Vol. 169, no. 1-4 (2006), p. 355-374
- Full Text: false
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- Description: A 10-month study of surface waters in Canadian Creek (Ballarat, Victoria, Australia) showed the significant influence of historic gold mining waste material. The investigation focussed on the hydrogeochemistry of the surface waters and soils in order to: (1) document the levels and seasonal trends in major, minor and trace elements in the creek, (2) identify the process by which As is released from the soil/waste mining material to surface waters. For most dissolved major and trace elements (Na, Ca, Mg, K, and As) in surface waters, the concentrations decreased with the increasing rainfall and flow conditions except for Al and Fe. Two sites selected along the creek (<1 km apart) allowed evaluation of the possibility that mining waste material is contributing to the elevated As concentrations (up to 145
- Description: C1
- Description: 2003001958
Arsenic and major cation hydrogeochemistry of the Central Victorian (Australia) surface waters
- Authors: Sultan, Khawar , Dowling, Kim
- Date: 2006
- Type: Text , Journal article
- Relation: Journal of Environmental Sciences Vol. 18, no. 1 (2006), p. 184-192
- Full Text: false
- Reviewed:
- Description: This paper reports on the major cations (Ca, Mg, Na and K) and arsenic (As) compositions of surface waters collected from major creeks, rivers and lakes in Central Victoria (Australia). The surface waters were found to be neutral to alkaline (pH 6.7-9.4), oxidised (average redox potential (Eh) about 130 mV) and showed variable concentrations of dissolved ions (EC, about 51-4386
- Description: C1
- Description: 2003002078