Characterization and recovery of gold associated with fine, activated carbon
- Authors: Rowe, James , McKnight, Stafford
- Date: 2009
- Type: Text , Conference paper
- Relation: Paper presented at World Gold Conference 2009, Johannesburg, South Africa : 26th-30th October 2009
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- Description: The attrition of activated carbon, and the loss of gold associated with it, is of significant economic importance to the operation of a CIP/CIL circuit. The focus of this study was on activated carbon recovered from an elution circuit which was deemed too fine for reuse. Results of cyclosizer and laser particle size analysis identified that most of the carbon was contained in the larger size fraction suggesting formation by abrasion. Digestion and AAS analysis of the individual size fractions identified a disproportionate concentration of gold in the finer size fractions which was identified by scanning electron microscopy to be due to the presence of fine metallic gold formed as a result of the acid washing process. Attempts to strip the remaining gold using sodium hydroxide or sodium sulphide based solutions proved unsuccessful due to poor elution efficiencies and re adsorption of gold. Upgrading of the material by froth flotation was also investigated using various conventional flotation reagents which had some success in concentrating the free metallic gold, however, grade and/or recoveries were considered less than desirable. Greater success was ultimately found in the transfer of gold from the fine carbon material onto coarser virgin activated carbon using a caustic cyanide solution. Sodium sulphide, sodium chloride and ammonium chloride based solutions were also trialled but proved less successful owing to their inability to mobilise metallic gold or gold cyanide species. Repetition of the transfer process proved capable of stripping 97% of the gold contained on the carbon fines for a bed volume ratio of 6:1.
- Description: 2003007482
Effect of spatial distribution of wax and PEG-isocyanate on the morphology and hydrophobicity of starch films
- Authors: Muscat, Delina , Adhikari, Raju , Tobin, Mark , McKnight, Stafford , Wakeling, Lara , Adhikari, Benu
- Date: 2014
- Type: Text , Journal article
- Relation: Carbohydrate Polymers Vol. 111, no. (2014), p. 333-347
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- Description: This study proposes a novel method for improving surface hydrophobicity of glycerol plasticized high amylose (HAG) films. We used polyethylene glycol isocyanate (PEG-iso) crosslinker to link HAG and three natural waxes (beeswax, candelilla wax and carnauba wax) to produce HAG + wax + PEG-iso films. The spatial distributions of wax and PEG-iso across the thickness of these films were determined using Synchrotron-based Fourier transform infrared spectroscopy. The hydrophobicity and surface morphology of the films were determined using contact angle (CA) and scanning electron microscopic measurements, respectively. The distribution patterns of wax and the PEG-iso across the thickness of the film, and the nature of crystalline patterns formed on the surface of these films were found to be the key factors affecting surface hydrophobicity. The highest hydrophobicity (CA >90°) was created when the PEG-iso was primarily distributed in the interior of the films and a hierarchical circular pinnacle structure of solidified wax was formed on the surface. © 2014 Elsevier Ltd.
Evolution of the boundary between the western and central Lachlan Orogen : Implications for tasmanide tectonics
- Authors: Spaggiari, Catherine , Gray, David , Foster, David , McKnight, Stafford
- Date: 2003
- Type: Text , Journal article
- Relation: Australian Journal of Earth Sciences Vol. 50, no. 5 (2003), p. 725-749
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- Description: Differences in oblique overprinting, along-strike complexity as well as structural, metamorphic and timing constraints suggest that the boundary between the western and central subprovinces of the Lachlan Orogen, currently designated by the Governor Fault, cannot be a single structure. Previously limited data on the nature and kinematics of the fault/shear systems defining the boundary have led to varying scenarios for the tectonic evolution of the Lachlan Orogen. These scenarios either involve large-scale strike-slip displacement along the boundary with subsequent overthrusting or convergence of oppositely vergent thrust-systems with limited strike-slip translation. Geometrical constraints, fabric chronology and kinematic indicators in both the Mt Wellington (Melbourne Zone) and Governor (Tabberabbera Zone) Fault Zones indicate that maximum displacements relate to thrusting and duplex formation, followed by minor strike-slip faulting perhaps in response to slightly oblique collision of the Melbourne and Tabberabbera structural zones. Collision of these zones took place between ca 400 and 390 Ma. At Howqua, structural relationships indicate that collision involved northeast-directed thrusting of the Melbourne Zone (Mt Wellington Fault Zone) over the Tabberabbera Zone (Governor Fault Zone), and was followed by regional, northwest-trending, open folding. These structures overprint the dominant fabrics and metamorphic assemblages that are interpreted to relate to disruption and underthrusting of Cambrian oceanic/arc crust during closure of a marginal basin. Major deformation in the Tabberabbera Zone took place from ca 445 Ma and was associated with mélange formation, underplating and imbrication or duplexing (Governor Fault Zone, East Howqua segmennt). At slightly higher crustal levels, and following deposition of Upper Ordovician black shale and chert sequences (ca 440 Ma), Tabberabbera Zone evolution included offscraping of a serpentinite body (Dolodrook segment) that may have been either a Marianas-style seamount or transform fault zone within the Cambrian oceanic/arc crust. Major thrusting in the Mt Wellington Fault Zone was underway sometime after ca 420 Ma, and in contrast to the Governor Fault Zone, no mélange or broken formation was produced, metamorphism was at slightly higher temperatures and deformation probably occurred under higher strain states.
- Description: C1
- Description: 2003000547
Geochemical characteristics and structural setting of lithium–caesium–tantalum pegmatites of the Dorchap Dyke Swarm, northeast Victoria, Australia
- Authors: Hines, Benjamin , Turnbull, D. , Ashworth, Luisa , McKnight, Stafford
- Date: 2023
- Type: Text , Journal article
- Relation: Australian Journal of Earth Sciences Vol. 70, no. 6 (2023), p. 763-800
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- Description: The Dorchap Dyke Swarm hosts the first recorded occurrence of lithium–caesium–tantalum (LCT) pegmatites in Victoria, Australia. Syn-orogenic emplacement of pegmatite dykes occurred along a northwest-trending shear system during the Benambran Orogeny. Pegmatites are derived from fractionated melt associated with the Mount Wills Granite, which is an S-type, peraluminous granite originating from supracrustal melting of Ordovician sedimentary sequences. A distinct, eastward-oriented fractionation trend across the Dorchap Dyke Swarm has highlighted a 20 × 8 km highly fractionated zone in the northeastern Dorchap Range, which includes spodumene- and petalite-bearing pegmatites. A distinct pattern of elemental enrichment (P > Cs > Be > Nb
Leven Star deposit: An example of Middle to Late Devonian intrusion-related gold systems in the western Lachlan Orogen, Victoria
- Authors: Whittam, R. R. , Bierlein, Frank , McKnight, Stafford
- Date: 2006
- Type: Text , Journal article
- Relation: Australian Journal of Earth Sciences Vol. 53, no. 2 (2006), p. 343-362
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- Description: This study documents an example of atypical gold mineralisation in the central Victorian gold province of the western Lachlan Orogen, Australia. Unlike the vast majority of orogenic gold deposits in this region, the Leven Star deposit at Malmsbury is characterised by a disseminated-stockwork style of mineralisation, a close spatial and temporal association with post-tectonic felsic intrusions, complex alteration characteristics and a Au-As-Sb (±Bi-Te-Cu-Zn-Pb-Sn-W) ore assemblage. In contrast to orogenic-style, metamorphism-related gold mineralisation (ca 440 Ma), which pre-dated magmatism in the western Lachlan Orogen by tens of millions of years, ore formation in the Leven Star deposit was synchronous with, and is paragenetically younger than, Middle to Late Devonian (ca 370 Ma) magmatism. On the basis of these timing relationships, as well as whole-rock geochemistry, and structural, petrographic and fluid-inclusion data, it is suggested that the Leven Star deposit is not orogenic in character and instead should be classified as intrusion-related. © Geological Society of Australia.
- Description: C1
- Description: 2003001628
Possible intrusion-related gold systems in the western Lachlan orogen, southeast Australia
- Authors: Bierlein, Frank , McKnight, Stafford
- Date: 2005
- Type: Text , Journal article
- Relation: Economic Geology Vol. 100, no. 2 (2005), p. 385-398
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- Description: Several gold deposits occurring in the western Lachlan orogen have geological, geochemical, and geochronological characteristics that distinguish them from typical vein-hosted orogenic gold deposits of the central Victorian gold province. The later are responsible for more than 90 percent, of primary (hard-rock) gold production from this region and are generally considered to represent the only economically significant type of gold deposit in the western Lach an orogen. Atypical gold occurrences at Malmsbury, Myrtle Creek, Mount Piper, and the Wonga deposit in the Stawell goldfield are characterized by a close spatial and temporal association with posttectonic felsic intrusions, disseminated to stockwork-style mineralization, alteration dominated by sericitization, sulfidation, silicification, carbonatization and tourmalinization, and associated complex An ± Mo-W-Bi-Te-Cu. The deposits have a number of features in common with intrusion-related gold deposits elsewhere in Phanerozoic orogenic belts. Although production from this type of gold mineralization in the western Lachlan orogen has been small compared to orogenic gold deposits, the possible existence of intrusion-related gold deposits has potentially important implications for exploration in this region and also provides significant clues to the tectonic framework and Paleozoic metallogeny of eastern Australia. © 2005 Society of Economic Geologists, Inc.
- Description: C1
- Description: 2003001065
Significance of monazite EPMA ages from the Quamby Conglomerate, Queensland
- Authors: Evins, P. M. , Wilde, A. R. , Foster, David , McKnight, Stafford , Blenkinsop, T. G.
- Date: 2007
- Type: Text , Journal article
- Relation: Australian Journal of Earth Sciences Vol. 54, no. 1 (2007), p. 19-26
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- Description: Th-U-Pb electron microprobe (EPMA) dating of mainly detrital monazite from the Quamby Conglomerate in the Eastern Succession of the Mt Isa inlier reveals three distinct monazite growth/recrystallisation events at around 1640, 1580 and 1490 Ma. These ages are particularly significant with respect to the timing of deposition, iron and gold mineralisation, and deformation in the Mt Isa inlier. The oldest age probably represents provenance from igneous rocks. In the sample, the majority of monazite growth occurred at 1580 Ma, coeval with peak metamorphism in the Eastern Succession. The low metamorphic grade of the conglomerate and wide compositional range of monazite bearing this age indicates that the monazite grew elsewhere and was later deposited in the conglomerate. Purple bands in the rock are composed mainly of coarse specular hematite with recrystallised margins that contribute to high (up to 20%) Fe2O3 contents in the conglomerate. Gold is also present in some of the samples. Some of the monazite grains contain small, younger (ca 1490 Ma) domains that may have grown/ recrystallised in situ during a lower grade syn- or post-diagenetic metamorphic/hydrothermal event that may have been related to hematite (re)crystallisation. Together, these ages bracket deposition of the Quamby Conglomerate to between ca 1580 and 1490 Ma, the latter age most likely representing diagenesis. This depositional age also represents a maximum age for north-south-striking, upright folds of the Quamby Conglomerate and implies that significant ductile deformation has affected parts of the Mt Isa inlier after 1580 Ma and probably after 1490 Ma.
- Description: C1
- Description: Creative work
- Description: 2003004832
The use of low-toxic heavy suspensions in mineral sands evaluation and zircon fractionation
- Authors: Koroznikova, Larissa , Klutke, Cameron , McKnight, Stafford , Hall, Stephen
- Date: 2008
- Type: Text , Journal article
- Relation: Journal of The South African Institute of Mining and Metallurgy Vol. 108, no. 1 (2008), p. 25-33
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- Description: This paper outlines a simple methodology for mineral characterization, developed as part of the Australian Mineral Industry Research Association (AMIRA) managed research project P777 'The Development of Heavy Suspension Techniques for High Density Separations (Replacement of Clerici's Solution)'. The project was sponsored by De Beers, Rio Tinto and Iluka Resources. Heavy mineral characterization of samples arising from exploration, mining or metallurgical processes is frequently conducted using laboratory heavy liquid analysis. Unfortunately, there are only a limited number of high density ('heavy') liquids and these tend to be more toxic as their density increases. Low-toxicity inorganic solutions, based on tungsten compounds, have been developed that can be utilized at relative densities (RD) up to 3.0. Beyond this value organic liquids can be used; however, this presents significant health and safety hazards. Diiodomethane (methylene iodide) having a relative density of 3.31 is commonly used. Mixtures of thallium formate and thallium malonate were found in the early 1900s by Clerici to provide liquids having specific gravities between 4.0 and 5.0. For the characterization of the heavy components of mineral sand deposits (e.g. anatase RD 3.9, rutile RD 4.2, ilmenite RD 4.4-4.7 and zircon RD 4.6-4.8) there is currently no heavy liquid alternative to Clerici's solution. Clerici's solution is highly toxic and testing is now conducted by few laboratories worldwide, with costs reflecting the chemical costs, infrastructure costs and health and safety regimes (e.g. blood testing of exposed staff). A simple laboratory technique of density fractionation has been developed, employing suspensions of fine tungsten carbide particles in lithium heteropolytungstates solutions, that can replace Clerici's solution in the evaluation of fine mineral sands samples (e.g. -250 +150 microns). The developing methodology that can achieve low-cost, low-toxic separations at relative densities above 4.0 is outlined and the comparison of results with Clerici's solution presented. In addition, preliminary work on density fractionation of zircon samples is presented. Zircon fractionation relates to their inclusion, radionuclide content and metamictization. © The Southern African Institute of Mining and Metallurgy, 2008.
- Description: C1