Chemical characterization of MEA degradation in PCC pilot plants operating in Australia
- Cruickshank, Alicia, Verheyen, Vincent, Adeloju, Samuel, Meuleman, Erik, Chaffee, Alan, Cottrell, Aaron, Feron, Paul
- Authors: Cruickshank, Alicia , Verheyen, Vincent , Adeloju, Samuel , Meuleman, Erik , Chaffee, Alan , Cottrell, Aaron , Feron, Paul
- Date: 2013
- Type: Text , Journal article
- Relation: Energy Procedia Vol. 37, no. (2013), p. 877-882
- Full Text:
- Reviewed:
- Description: An important step towards commercial scale post-combustion CO2 capture from coal-fired power stations is understanding solvent degradation. Laboratory scale trials have identified three main solvent degradation pathways for 30% MEA: oxidative degradation, carbamate polymerization and formation of heat stable salts. This paper probes the semi-volatile organic compounds produced from a single batch of 30% MEA which was used to capture CO2 from a black coal-fired power station (Tarong, Queensland, Australia) for approximately 700 hours, followed by 500 hours at the brown coal-fired power station (Loy Yang, Victoria, Australia). Comparisons are made between the compounds identified in this aged solvent system with MEA degradation reactions described in literature. Most of semi-volatile compounds tentatively identified by GC/MS have previously been reported in laboratory scale degradation trials. Our preliminary results show low levels of degradation products were present in samples after its use in the pilot plant at Tarong (black coal) and consequent 13 months storage, but much higher concentrations were later found in the same solvent during its at use in the pilot plant at Loy Yang Power (brown coal). Further work includes identifying the cause of poor GC/MS repeatability and investigating the relative rates of reactions described in literature. The impact of inorganic anions and dissolved metals on MEA degradation will also be explored.
- Authors: Cruickshank, Alicia , Verheyen, Vincent , Adeloju, Samuel , Meuleman, Erik , Chaffee, Alan , Cottrell, Aaron , Feron, Paul
- Date: 2013
- Type: Text , Journal article
- Relation: Energy Procedia Vol. 37, no. (2013), p. 877-882
- Full Text:
- Reviewed:
- Description: An important step towards commercial scale post-combustion CO2 capture from coal-fired power stations is understanding solvent degradation. Laboratory scale trials have identified three main solvent degradation pathways for 30% MEA: oxidative degradation, carbamate polymerization and formation of heat stable salts. This paper probes the semi-volatile organic compounds produced from a single batch of 30% MEA which was used to capture CO2 from a black coal-fired power station (Tarong, Queensland, Australia) for approximately 700 hours, followed by 500 hours at the brown coal-fired power station (Loy Yang, Victoria, Australia). Comparisons are made between the compounds identified in this aged solvent system with MEA degradation reactions described in literature. Most of semi-volatile compounds tentatively identified by GC/MS have previously been reported in laboratory scale degradation trials. Our preliminary results show low levels of degradation products were present in samples after its use in the pilot plant at Tarong (black coal) and consequent 13 months storage, but much higher concentrations were later found in the same solvent during its at use in the pilot plant at Loy Yang Power (brown coal). Further work includes identifying the cause of poor GC/MS repeatability and investigating the relative rates of reactions described in literature. The impact of inorganic anions and dissolved metals on MEA degradation will also be explored.
Phosphorus distribution in soils from Australian dairy and beef rearing pastoral systems
- Adeloju, Samuel, Webb, Benjamin, Smernik, Ronald
- Authors: Adeloju, Samuel , Webb, Benjamin , Smernik, Ronald
- Date: 2016
- Type: Text , Journal article
- Relation: Applied Sciences (Switzerland) Vol. 6, no. 2 (2016), p. 1-19
- Full Text:
- Reviewed:
- Description: The influence of soil type and management practices on P distribution in soils from Australian dairy and beef rearing pastoral systems has been investigated by chemical measurements and phosphorus-31 (31P) nuclear magnetic resonance (NMR) spectroscopy. The amount and forms of P within the soil profile varied with soil type, with the acidic red Ferrosols containing relatively high orthophosphate concentrations, averaging 72.2% compared with 66.8% for Dermosols, under similar management conditions. Soil from Sodosol sites which received less fertiliser P addition had the lowest orthophosphate concentration with only 57.6%. In contrast, relatively high proportions of organic P were found in soil samples from unfertilised Sodosol sites. On average, soil from Sodosol sites contained 37.5% organic P (combined monoester P and diester P), while those from Dermosol and Ferrosol sites contained 31.7% and 25.8%, respectively. Of these, the highest monoester phosphate proportions of 44.6% (site M3) and 46.4% (site M4) were found in Sodosol sites with no recent P inputs, but the highest proportion of diester phosphate (5.7%) was found in an unclassified grey sandy loam Dermosol. The higher organic P concentrations in soil from Sodosol sites may be associated with more regular moisture input from both rainfall and boarder-check (flood) irrigation. The highest level of pyrophosphate (8.5%) was also found in a grey/yellow Sodosol. Overall, the results indicate that P speciation in the Australian soils is strongly influenced by soil type, fertiliser P application rate and timing, and moisture variations. © 2016 by the authors; licensee MDPI, Basel, Switzerland.
- Authors: Adeloju, Samuel , Webb, Benjamin , Smernik, Ronald
- Date: 2016
- Type: Text , Journal article
- Relation: Applied Sciences (Switzerland) Vol. 6, no. 2 (2016), p. 1-19
- Full Text:
- Reviewed:
- Description: The influence of soil type and management practices on P distribution in soils from Australian dairy and beef rearing pastoral systems has been investigated by chemical measurements and phosphorus-31 (31P) nuclear magnetic resonance (NMR) spectroscopy. The amount and forms of P within the soil profile varied with soil type, with the acidic red Ferrosols containing relatively high orthophosphate concentrations, averaging 72.2% compared with 66.8% for Dermosols, under similar management conditions. Soil from Sodosol sites which received less fertiliser P addition had the lowest orthophosphate concentration with only 57.6%. In contrast, relatively high proportions of organic P were found in soil samples from unfertilised Sodosol sites. On average, soil from Sodosol sites contained 37.5% organic P (combined monoester P and diester P), while those from Dermosol and Ferrosol sites contained 31.7% and 25.8%, respectively. Of these, the highest monoester phosphate proportions of 44.6% (site M3) and 46.4% (site M4) were found in Sodosol sites with no recent P inputs, but the highest proportion of diester phosphate (5.7%) was found in an unclassified grey sandy loam Dermosol. The higher organic P concentrations in soil from Sodosol sites may be associated with more regular moisture input from both rainfall and boarder-check (flood) irrigation. The highest level of pyrophosphate (8.5%) was also found in a grey/yellow Sodosol. Overall, the results indicate that P speciation in the Australian soils is strongly influenced by soil type, fertiliser P application rate and timing, and moisture variations. © 2016 by the authors; licensee MDPI, Basel, Switzerland.
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