Experimental evaluation of methods for reclaiming sulfur loaded amine absorbents
- Garg, Bharti, Pearson, Pauline, Cousins, Ashleigh, Verheyen, Vincent, Puxty, Graeme, Feron, Paul
- Authors: Garg, Bharti , Pearson, Pauline , Cousins, Ashleigh , Verheyen, Vincent , Puxty, Graeme , Feron, Paul
- Date: 2018
- Type: Text , Conference proceedings , Conference paper
- Relation: 14th Greenhouse Gas Control Technologies Conference (GHGT-14); Melbourne, Australia; 21st-26th October 2018 p. 1-8
- Full Text:
- Reviewed:
- Description: Sulfur dioxide (SO2) is a major flue gas contaminant that has a direct effect on the performance of amine-based carbon dioxide capture units operating on power plant flue gases. In many countries, flue gas desulfurisation (FGD) is an essential upstream requirement to CO2 capture systems, thereby increasing the overall operational and capital cost of the capture system. In Australia, the efficacy of CO2 capture may be compromised by the accumulation of SO2 in the absorption solvent. CSIRO’s CS-Cap process is designed to capture of both these acidic gases in one absorption column, thereby eliminating the need for a separate FGD unit which could potentially save millions of dollars. Previous research at CSIRO’s post-combustion capture pilot plant at Loy Yang power station has shown that mono-ethanolamine (MEA) solvent absorbs both CO2 and SO2, resulting in a spent amine absorbent rich in sulfates. Further development of the CS-Cap concept requires a deeper understanding of the properties of the sulfate-rich absorbent and the conditions under which it can be effectively regenerated. In the present study, thermal reclamation and reactive crystallisation processes were investigated, allowing the parameters affecting the regeneration of sulfate-loaded amine to be identified. It was found that amine losses were considerably higher in thermal reclamation than in reactive precipitation. During thermal reclamation, vacuum conditions were more effective than atmospheric, and pH of the initial solution played a significant role in recovery of MEA from the sulfate-rich absorbent. Reactive crystallisation could be effectively accomplished with the addition of KOH. An advantage of this process was that high purity K2SO4 crystals (~99%) were formed, despite the presence of degradation products in the solvent.
- Authors: Garg, Bharti , Pearson, Pauline , Cousins, Ashleigh , Verheyen, Vincent , Puxty, Graeme , Feron, Paul
- Date: 2018
- Type: Text , Conference proceedings , Conference paper
- Relation: 14th Greenhouse Gas Control Technologies Conference (GHGT-14); Melbourne, Australia; 21st-26th October 2018 p. 1-8
- Full Text:
- Reviewed:
- Description: Sulfur dioxide (SO2) is a major flue gas contaminant that has a direct effect on the performance of amine-based carbon dioxide capture units operating on power plant flue gases. In many countries, flue gas desulfurisation (FGD) is an essential upstream requirement to CO2 capture systems, thereby increasing the overall operational and capital cost of the capture system. In Australia, the efficacy of CO2 capture may be compromised by the accumulation of SO2 in the absorption solvent. CSIRO’s CS-Cap process is designed to capture of both these acidic gases in one absorption column, thereby eliminating the need for a separate FGD unit which could potentially save millions of dollars. Previous research at CSIRO’s post-combustion capture pilot plant at Loy Yang power station has shown that mono-ethanolamine (MEA) solvent absorbs both CO2 and SO2, resulting in a spent amine absorbent rich in sulfates. Further development of the CS-Cap concept requires a deeper understanding of the properties of the sulfate-rich absorbent and the conditions under which it can be effectively regenerated. In the present study, thermal reclamation and reactive crystallisation processes were investigated, allowing the parameters affecting the regeneration of sulfate-loaded amine to be identified. It was found that amine losses were considerably higher in thermal reclamation than in reactive precipitation. During thermal reclamation, vacuum conditions were more effective than atmospheric, and pH of the initial solution played a significant role in recovery of MEA from the sulfate-rich absorbent. Reactive crystallisation could be effectively accomplished with the addition of KOH. An advantage of this process was that high purity K2SO4 crystals (~99%) were formed, despite the presence of degradation products in the solvent.
Simulating combined SO2 and CO2 capture from combustion flue gas
- Verheyen, Vincent, Cousins, Ashleigh, Pearson, Pauline, Puxty, Graeme, Jiang, Kaiqi, Garg, Bharti, Zhai, Rongrong, Ott, Petro, Feron, Paul
- Authors: Verheyen, Vincent , Cousins, Ashleigh , Pearson, Pauline , Puxty, Graeme , Jiang, Kaiqi , Garg, Bharti , Zhai, Rongrong , Ott, Petro , Feron, Paul
- Date: 2019
- Type: Text , Journal article
- Relation: Greenhouse Gases : Science and Technology Vol. 9, no. 6 (2019), p. 1087-1095
- Full Text:
- Reviewed:
- Description: The requirement to pre‐treat flue gas prior to the CO2 capture step is an economic challenge when using aqueous amine absorbents for capturing CO2 from coal‐fired power station flue gases. A potentially lower cost alternative is to combine the capture of both CO2 and SO2 from the flue gas into a single process, removing the requirement for the desulfurization pre‐treatment step. The CSIRO's CS‐Cap process uses a single aqueous amine absorbent to capture both of these acid gases from flue gas streams. This paper covers the initial simulation of this process applied to both brown and black coal flue gases. Removal of absorbed SO2 is achieved via reactive crystallization. This is simulated here using a ‘black box’ process, resulting in a K2SO4 product. Different operating conditions have been evaluated that increase the sulfate concentration of the absorbent in the SO2 capture section of the process, which is expected to increase the efficiency of the reactive crystallization step. This paper provides information on the absorption of SO2 into the amine solution, and heat and mass balances for the wider process. This information will be required for further detailed simulation of the reactive crystallization step, and economic evaluation of the CS‐Cap process. © 2019 Society of Chemical Industry and John Wiley & Sons, Ltd.
- Authors: Verheyen, Vincent , Cousins, Ashleigh , Pearson, Pauline , Puxty, Graeme , Jiang, Kaiqi , Garg, Bharti , Zhai, Rongrong , Ott, Petro , Feron, Paul
- Date: 2019
- Type: Text , Journal article
- Relation: Greenhouse Gases : Science and Technology Vol. 9, no. 6 (2019), p. 1087-1095
- Full Text:
- Reviewed:
- Description: The requirement to pre‐treat flue gas prior to the CO2 capture step is an economic challenge when using aqueous amine absorbents for capturing CO2 from coal‐fired power station flue gases. A potentially lower cost alternative is to combine the capture of both CO2 and SO2 from the flue gas into a single process, removing the requirement for the desulfurization pre‐treatment step. The CSIRO's CS‐Cap process uses a single aqueous amine absorbent to capture both of these acid gases from flue gas streams. This paper covers the initial simulation of this process applied to both brown and black coal flue gases. Removal of absorbed SO2 is achieved via reactive crystallization. This is simulated here using a ‘black box’ process, resulting in a K2SO4 product. Different operating conditions have been evaluated that increase the sulfate concentration of the absorbent in the SO2 capture section of the process, which is expected to increase the efficiency of the reactive crystallization step. This paper provides information on the absorption of SO2 into the amine solution, and heat and mass balances for the wider process. This information will be required for further detailed simulation of the reactive crystallization step, and economic evaluation of the CS‐Cap process. © 2019 Society of Chemical Industry and John Wiley & Sons, Ltd.
Regeneration of sulfate-rich postcombustion capture amines through reactive crystallisation
- Garg, Bharti, Pearson, Pauline, Cousins, Ashleigh, McKnight, Stafford, Verheyen, Vincent
- Authors: Garg, Bharti , Pearson, Pauline , Cousins, Ashleigh , McKnight, Stafford , Verheyen, Vincent
- Date: 2020
- Type: Text , Journal article
- Relation: Asia-Pacific Journal of Chemical Engineering Vol. 15, no. 6 (2020), p.
- Full Text: false
- Reviewed:
- Description: Flue gas desulfurisation is a prerequisite for successful CO2 capture in coal-fired power stations utilising aqueous amine absorbents. For nations like Australia, where there is nonexistence of mandatory flue gas desulfurisation, this increases the cost for power plants retrofitting CO2 capture. The CSIRO's CS-Cap process, a potentially low cost method for combined CO2 and SO2 capture, provides an alternate sulfur management solution to such plants. The CS-Cap process, however, results in high sulfur-loaded amines that require continuous regeneration to retain cost benefits. Reactive crystallisation by KOH addition is shown to be successful in removing the bulk of the sulfate from aqueous amines without any additional heating or cooling requirements. Increasing initial sulfate loading by amine recycling initially improves sulfate removal efficiency, up to the postsaturation level where the systems ionic strength determines further sulfate solubility. Oxidative amine degradation had no significant effect on the precipitation efficiency or purity of K2SO4 crystals apart from their slight discoloration. The behaviour of the residual potassium in these regenerated aqueous amines needs further investigation as it could lead to unwanted precipitation inside the absorber column and other parts of the process. © 2020 Curtin University and John Wiley & Sons, Ltd.
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