The use of low-toxic heavy suspensions in mineral sands evaluation and zircon fractionation
- Koroznikova, Larissa, Klutke, Cameron, McKnight, Stafford, Hall, Stephen
- Authors: Koroznikova, Larissa , Klutke, Cameron , McKnight, Stafford , Hall, Stephen
- Date: 2008
- Type: Text , Journal article
- Relation: Journal of The South African Institute of Mining and Metallurgy Vol. 108, no. 1 (2008), p. 25-33
- Full Text:
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- Description: This paper outlines a simple methodology for mineral characterization, developed as part of the Australian Mineral Industry Research Association (AMIRA) managed research project P777 'The Development of Heavy Suspension Techniques for High Density Separations (Replacement of Clerici's Solution)'. The project was sponsored by De Beers, Rio Tinto and Iluka Resources. Heavy mineral characterization of samples arising from exploration, mining or metallurgical processes is frequently conducted using laboratory heavy liquid analysis. Unfortunately, there are only a limited number of high density ('heavy') liquids and these tend to be more toxic as their density increases. Low-toxicity inorganic solutions, based on tungsten compounds, have been developed that can be utilized at relative densities (RD) up to 3.0. Beyond this value organic liquids can be used; however, this presents significant health and safety hazards. Diiodomethane (methylene iodide) having a relative density of 3.31 is commonly used. Mixtures of thallium formate and thallium malonate were found in the early 1900s by Clerici to provide liquids having specific gravities between 4.0 and 5.0. For the characterization of the heavy components of mineral sand deposits (e.g. anatase RD 3.9, rutile RD 4.2, ilmenite RD 4.4-4.7 and zircon RD 4.6-4.8) there is currently no heavy liquid alternative to Clerici's solution. Clerici's solution is highly toxic and testing is now conducted by few laboratories worldwide, with costs reflecting the chemical costs, infrastructure costs and health and safety regimes (e.g. blood testing of exposed staff). A simple laboratory technique of density fractionation has been developed, employing suspensions of fine tungsten carbide particles in lithium heteropolytungstates solutions, that can replace Clerici's solution in the evaluation of fine mineral sands samples (e.g. -250 +150 microns). The developing methodology that can achieve low-cost, low-toxic separations at relative densities above 4.0 is outlined and the comparison of results with Clerici's solution presented. In addition, preliminary work on density fractionation of zircon samples is presented. Zircon fractionation relates to their inclusion, radionuclide content and metamictization. © The Southern African Institute of Mining and Metallurgy, 2008.
- Description: C1
- Authors: Koroznikova, Larissa , Klutke, Cameron , McKnight, Stafford , Hall, Stephen
- Date: 2008
- Type: Text , Journal article
- Relation: Journal of The South African Institute of Mining and Metallurgy Vol. 108, no. 1 (2008), p. 25-33
- Full Text:
- Reviewed:
- Description: This paper outlines a simple methodology for mineral characterization, developed as part of the Australian Mineral Industry Research Association (AMIRA) managed research project P777 'The Development of Heavy Suspension Techniques for High Density Separations (Replacement of Clerici's Solution)'. The project was sponsored by De Beers, Rio Tinto and Iluka Resources. Heavy mineral characterization of samples arising from exploration, mining or metallurgical processes is frequently conducted using laboratory heavy liquid analysis. Unfortunately, there are only a limited number of high density ('heavy') liquids and these tend to be more toxic as their density increases. Low-toxicity inorganic solutions, based on tungsten compounds, have been developed that can be utilized at relative densities (RD) up to 3.0. Beyond this value organic liquids can be used; however, this presents significant health and safety hazards. Diiodomethane (methylene iodide) having a relative density of 3.31 is commonly used. Mixtures of thallium formate and thallium malonate were found in the early 1900s by Clerici to provide liquids having specific gravities between 4.0 and 5.0. For the characterization of the heavy components of mineral sand deposits (e.g. anatase RD 3.9, rutile RD 4.2, ilmenite RD 4.4-4.7 and zircon RD 4.6-4.8) there is currently no heavy liquid alternative to Clerici's solution. Clerici's solution is highly toxic and testing is now conducted by few laboratories worldwide, with costs reflecting the chemical costs, infrastructure costs and health and safety regimes (e.g. blood testing of exposed staff). A simple laboratory technique of density fractionation has been developed, employing suspensions of fine tungsten carbide particles in lithium heteropolytungstates solutions, that can replace Clerici's solution in the evaluation of fine mineral sands samples (e.g. -250 +150 microns). The developing methodology that can achieve low-cost, low-toxic separations at relative densities above 4.0 is outlined and the comparison of results with Clerici's solution presented. In addition, preliminary work on density fractionation of zircon samples is presented. Zircon fractionation relates to their inclusion, radionuclide content and metamictization. © The Southern African Institute of Mining and Metallurgy, 2008.
- Description: C1
An investigation of correlation factors linking footing resistance on sand with cone penetration test results
- Gavin, Kenneth, Tolooiyan, Ali
- Authors: Gavin, Kenneth , Tolooiyan, Ali
- Date: 2012
- Type: Text , Journal article
- Relation: Computers and Geotechnics Vol. 46, no. (2012), p. 84-92
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- Description: Significant research effort has led to improvements in our ability to estimate the ultimate bearing resistance of footings in sand. These techniques often estimate the footing resistance at relatively large displacements, typically 10% of the footing width, q b0.1. Cone Penetration Test (CPT) design methods typically link q b0.1 and q c through a constant reduction factor, α. A range of α factors for shallow footings have been proposed, some methods suggest that α is constant and while others that it varies with footing width and depth (or stress level). There is a dearth of field data with which to compare these correlation factors, in particular where foundation width and depth have been varied in the same ground conditions. For this reason finite element analyses have proven to be a useful tool for performing the parametric studies required to asses factors controlling α. This paper describes the results of numerical analyses performed to investigate α factors for soil profiles which were calibrated using the results of the CPT tests performed at a dense sand test-bed site. The numerical model was first used to perform parametric analyses to consider the effect of footing width, B and footing depth, D on the α factor mobilised in dense Blessington sand. In order to assess the effects of relative density, footing tests in a range of natural sands with variable in situ densities were modeled. The results of the finite element analyses suggest that a direct correlation between q b0.1 and q c can be established at a given test site which is independent of footing width and depth and is relatively weakly dependent on the sands relative density if the zone of influence of the foundation considered is large enough. © 2012 Elsevier Ltd.
- Authors: Gavin, Kenneth , Tolooiyan, Ali
- Date: 2012
- Type: Text , Journal article
- Relation: Computers and Geotechnics Vol. 46, no. (2012), p. 84-92
- Full Text:
- Reviewed:
- Description: Significant research effort has led to improvements in our ability to estimate the ultimate bearing resistance of footings in sand. These techniques often estimate the footing resistance at relatively large displacements, typically 10% of the footing width, q b0.1. Cone Penetration Test (CPT) design methods typically link q b0.1 and q c through a constant reduction factor, α. A range of α factors for shallow footings have been proposed, some methods suggest that α is constant and while others that it varies with footing width and depth (or stress level). There is a dearth of field data with which to compare these correlation factors, in particular where foundation width and depth have been varied in the same ground conditions. For this reason finite element analyses have proven to be a useful tool for performing the parametric studies required to asses factors controlling α. This paper describes the results of numerical analyses performed to investigate α factors for soil profiles which were calibrated using the results of the CPT tests performed at a dense sand test-bed site. The numerical model was first used to perform parametric analyses to consider the effect of footing width, B and footing depth, D on the α factor mobilised in dense Blessington sand. In order to assess the effects of relative density, footing tests in a range of natural sands with variable in situ densities were modeled. The results of the finite element analyses suggest that a direct correlation between q b0.1 and q c can be established at a given test site which is independent of footing width and depth and is relatively weakly dependent on the sands relative density if the zone of influence of the foundation considered is large enough. © 2012 Elsevier Ltd.
A comparison of grain-size analysis methods for sand-dominated fluvial sediments
- Cheetham, Michael, Keene, Annabelle, Bush, Richard, Sullivan, Leigh, Erskine, Wayne
- Authors: Cheetham, Michael , Keene, Annabelle , Bush, Richard , Sullivan, Leigh , Erskine, Wayne
- Date: 2008
- Type: Text , Journal article
- Relation: Sedimentology Vol. 55, no. 6 (2008), p. 1905-1913
- Full Text: false
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- Description: Grain-size distribution is a fundamental tool for interpreting sedimentary units within depositional systems. The techniques assessed in this study are commonly used to determine grain-size distributions for sand-dominated sediments. However, the degree of consistency and differences in interpretation when using a combination of grain-size methods have not yet been assessed systematically for sand-dominated fluvial sediments. Results obtained from laser diffraction, X-ray attenuation and scanning electron microscopy grain-size analysis techniques were compared with those obtained from the traditional sieve/ hydrometer method. Scanning electron microscopy was shown to provide an inaccurate quantitative analysis of grain-size distributions because of difficulties in obtaining representative samples for examination. The X-ray attenuation method is unsuitable for sand-dominated sediments because of its upper size range of only 300 μm. The consistently strong correlation between the laser diffraction results and the sieve/ hydrometer results shows that these methods are comparable for sand-dominated fluvial sediments. Provided that sample preparation is consistent, the latter two methods can be used together within a study of such sediments while maintaining a high degree of accuracy. These results indicate that data for sand-dominated fluvial sediments gained from the long-established sieve/hydrometer method can be compared with confidence to those obtained by modern studies using laser diffraction techniques. © Journal compilation © 2008 International Association of Sedimentologists.
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