Determination of soil hydraulic parameters and evaluation of water dynamics and nitrate leaching in the unsaturated layered zone: A modeling case study in Central Croatia
- Defterdarović, Jasmina, Filipović, Lana, Kranjčec, Filip, Ondrašek, Gabrijel, Kikić, Diana, Novosel, Alen, Mustać, Ivan, Krevh, Vedran, Magdić, Ivan, Rubinić, Vedran, Bogunović, Igor, Dugan, Ivan, Čopec, Krešimir, He, Hailong, Filipović, Vilim
- Authors: Defterdarović, Jasmina , Filipović, Lana , Kranjčec, Filip , Ondrašek, Gabrijel , Kikić, Diana , Novosel, Alen , Mustać, Ivan , Krevh, Vedran , Magdić, Ivan , Rubinić, Vedran , Bogunović, Igor , Dugan, Ivan , Čopec, Krešimir , He, Hailong , Filipović, Vilim
- Date: 2021
- Type: Journal article
- Relation: Sustainability (Basel, Switzerland) Vol. 13, no. 12 (2021), p. 6688
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- Description: Nitrate leaching through soil layers to groundwater may cause significant degradation of natural resources. The aims of this study were: (i) to estimate soil hydraulic properties (SHPs) of the similar soil type with same management on various locations (ii) to determine annual water dynamics and (iii) to estimate the impact of subsoil horizon properties on nitrate leaching. The final goal was to compare the influence of different SHPs and layering on water dynamics and nitrate leaching. The study was conducted in central Croatia (Zagreb), at four locations on Calcaric Phaeozem, Calcaric Regosol, and Calcaric Fluvic Phaeozem soil types. Soil hydraulic parameters were estimated using the HYPROP system and HYPROP-FIT software. Water dynamics and nitrate leaching were evaluated using HYDRUS 2D/3D during a period of 365 days. The amount of water in the soil under saturated conditions varied from 0.422 to 0.535 cm3 cm−3 while the hydraulic conductivity varied from 3 cm day−1 to 990.9 cm day−1. Even though all locations have the same land use and climatic conditions with similar physical properties, hydraulic parameters varied substantially. The amount and velocity of transported nitrate (HYDRUS 2D/3D) were affected by reduced hydraulic conductivity of the subsoil as nitrates are primarily transported via advective flux. Despite the large differences in SHPs of the topsoil layers, the deeper soil layers, having similar SHPs, imposed a buffering effect preventing faster nitrate downward transport. This contributed to a very similar distribution of nitrates through the soil profile at the end of simulation period. This case study indicated the importance of carefully selecting relevant parameters in multilayered soil systems when evaluating groundwater pollution risk.
- Authors: Defterdarović, Jasmina , Filipović, Lana , Kranjčec, Filip , Ondrašek, Gabrijel , Kikić, Diana , Novosel, Alen , Mustać, Ivan , Krevh, Vedran , Magdić, Ivan , Rubinić, Vedran , Bogunović, Igor , Dugan, Ivan , Čopec, Krešimir , He, Hailong , Filipović, Vilim
- Date: 2021
- Type: Journal article
- Relation: Sustainability (Basel, Switzerland) Vol. 13, no. 12 (2021), p. 6688
- Full Text:
- Reviewed:
- Description: Nitrate leaching through soil layers to groundwater may cause significant degradation of natural resources. The aims of this study were: (i) to estimate soil hydraulic properties (SHPs) of the similar soil type with same management on various locations (ii) to determine annual water dynamics and (iii) to estimate the impact of subsoil horizon properties on nitrate leaching. The final goal was to compare the influence of different SHPs and layering on water dynamics and nitrate leaching. The study was conducted in central Croatia (Zagreb), at four locations on Calcaric Phaeozem, Calcaric Regosol, and Calcaric Fluvic Phaeozem soil types. Soil hydraulic parameters were estimated using the HYPROP system and HYPROP-FIT software. Water dynamics and nitrate leaching were evaluated using HYDRUS 2D/3D during a period of 365 days. The amount of water in the soil under saturated conditions varied from 0.422 to 0.535 cm3 cm−3 while the hydraulic conductivity varied from 3 cm day−1 to 990.9 cm day−1. Even though all locations have the same land use and climatic conditions with similar physical properties, hydraulic parameters varied substantially. The amount and velocity of transported nitrate (HYDRUS 2D/3D) were affected by reduced hydraulic conductivity of the subsoil as nitrates are primarily transported via advective flux. Despite the large differences in SHPs of the topsoil layers, the deeper soil layers, having similar SHPs, imposed a buffering effect preventing faster nitrate downward transport. This contributed to a very similar distribution of nitrates through the soil profile at the end of simulation period. This case study indicated the importance of carefully selecting relevant parameters in multilayered soil systems when evaluating groundwater pollution risk.
Modeling water flow and phosphorus sorption in a soil amended with sewage sludge and olive pomace as compost or biochar
- Filipović, Vilim, Černe, Marko, Šimůnek, Jiří, Filipović, Lana, Romić, Marija, Ondrašek, Gabrijel, Bogunović, Igor, Mustać, Ivan, Krevh, Vedran, Ferenčević, Anja, Robinson, David, Palčić, Igor, Pasković, Igor, Goreta Ban, Smiljana, Užila, Zoran, Ban, Dean
- Authors: Filipović, Vilim , Černe, Marko , Šimůnek, Jiří , Filipović, Lana , Romić, Marija , Ondrašek, Gabrijel , Bogunović, Igor , Mustać, Ivan , Krevh, Vedran , Ferenčević, Anja , Robinson, David , Palčić, Igor , Pasković, Igor , Goreta Ban, Smiljana , Užila, Zoran , Ban, Dean
- Date: 2020
- Type: Text , Journal article
- Relation: Agronomy (Basel) Vol. 10, no. 8 (2020), p. 1163
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- Description: Organic amendments are often reported to improve soil properties, promote plant growth, and improve crop yield. This study aimed to investigate the effects of the biochar and compost produced from sewage sludge and olive pomace on soil hydraulic properties, water flow, and P transport (i.e., sorption) using numerical modeling (HYDRUS-1D) applied to two soil types (Terra Rosa and Rendzina). Evaporation and leaching experiments on soil cores and repacked soil columns were performed to determine the soil water retention, hydraulic conductivity, P leaching potential, and P sorption capacity of these mixtures. In the majority of treatments, the soil water retention showed a small increase compared to the control soil. A reliable fit with the modified van Genuchten model was found, which was also confirmed by water flow modeling of leaching experiments (R2 0.99). The results showed a high P sorption in all the treatments (Kd 21.24 to 53.68 cm3 g−1), and a high model reliability when the inverse modeling procedure was used (R2 0.93–0.99). Overall, adding sewage sludge or olive pomace as compost or biochar improved the Terra Rosa and Rendzina water retention and did not increase the P mobility in these soils, proving to be a sustainable source of carbon and P-rich materials.
- Authors: Filipović, Vilim , Černe, Marko , Šimůnek, Jiří , Filipović, Lana , Romić, Marija , Ondrašek, Gabrijel , Bogunović, Igor , Mustać, Ivan , Krevh, Vedran , Ferenčević, Anja , Robinson, David , Palčić, Igor , Pasković, Igor , Goreta Ban, Smiljana , Užila, Zoran , Ban, Dean
- Date: 2020
- Type: Text , Journal article
- Relation: Agronomy (Basel) Vol. 10, no. 8 (2020), p. 1163
- Full Text:
- Reviewed:
- Description: Organic amendments are often reported to improve soil properties, promote plant growth, and improve crop yield. This study aimed to investigate the effects of the biochar and compost produced from sewage sludge and olive pomace on soil hydraulic properties, water flow, and P transport (i.e., sorption) using numerical modeling (HYDRUS-1D) applied to two soil types (Terra Rosa and Rendzina). Evaporation and leaching experiments on soil cores and repacked soil columns were performed to determine the soil water retention, hydraulic conductivity, P leaching potential, and P sorption capacity of these mixtures. In the majority of treatments, the soil water retention showed a small increase compared to the control soil. A reliable fit with the modified van Genuchten model was found, which was also confirmed by water flow modeling of leaching experiments (R2 0.99). The results showed a high P sorption in all the treatments (Kd 21.24 to 53.68 cm3 g−1), and a high model reliability when the inverse modeling procedure was used (R2 0.93–0.99). Overall, adding sewage sludge or olive pomace as compost or biochar improved the Terra Rosa and Rendzina water retention and did not increase the P mobility in these soils, proving to be a sustainable source of carbon and P-rich materials.
The effect of stabilization on the utilization of municipal sewage sludge as a soil amendment
- Černe, Marko, Palčić, Igor, Pasković, Igor, Major, Nikola, Romić, Marija, Filipović, Vilim, Igrc, Marina Diana, Perčin, Aleksandra, Goreta Ban, Smiljana, Zorko, Benjamin, Vodenik, Branko, Glavič Cindro, Denis, Milačič, Radmila, Heath, David John, Ban, Dean
- Authors: Černe, Marko , Palčić, Igor , Pasković, Igor , Major, Nikola , Romić, Marija , Filipović, Vilim , Igrc, Marina Diana , Perčin, Aleksandra , Goreta Ban, Smiljana , Zorko, Benjamin , Vodenik, Branko , Glavič Cindro, Denis , Milačič, Radmila , Heath, David John , Ban, Dean
- Date: 2019
- Type: Text , Journal article
- Relation: Waste Management Vol. 94, no. (2019), p. 27-38
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- Description: Stabilization procedures affect nutrient and inorganic contaminant concentrations.•Anaerobic sludge has the highest levels of metals and radionuclides.•High P and N contents in sludge are a measure of its potential as a fertilizer.•Adsorption of metals and radionuclides to sludge biomass increases with nutrient content.•Soil amendment with sewage sludge is a promising strategy for nutrient recovery. This study assesses the potential use of different types of stabilized sewage sludge as a soil amendment by considering their physicochemical characteristics, nutritional status, and their trace metal and radionuclide content. The concentrations of trace metals and radionuclides were determined using ICP-OES and gamma-ray spectrometry, respectively. For determining nutritional status and chemical characterization, this study followed standard ISO-recommended procedures. Data analysis revealed that anaerobic sludge contains higher concentrations of Cr, Hg, and Ni compared to aerobic and non-biologically stabilized sludge. A similar observation was observed in the case of 226Ra, 210Pb, 228Ra, and 228Th. Furthermore, the high levels of P and N in aerobic sludge suggest that biologically stabilized sludge has the potential to be a good fertilizer. In addition, the study finds strong evidence that nutrients are involved in the adsorption of metals and radionuclides onto sludge biomass. Overall, eight of the nine studied sludge samples are safe for agricultural use since the concentrations of trace metals fall well below the limits set by Croatian legislation (NN 38/08). In addition, the levels of radionuclides do not pose a radiological risk. This means that soil conditioning with sewage sludge remains a viable strategy for nutrient recovery from municipal waste, although long-term impact assessments of repeated applications are necessary.
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